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There are several budget travel options from Bangkok to Rong Klue Market/Poipet.
At Rong Kluea.
The bus station at Rong Kluea is about 1km from the actual border. If you arrive with little luggage, you might want to take an interesting walk to the border, through the HUGE market, which sells a wide variety of new and used clothes, bags, shoes and other products, including food & fruits. Many of the small retail trader from Bangkok and other provinces make their way here frequently to buy products wholesale. This is also the last place to catch Thai food before crossing into Cambodia (where the food is very different).
If you have luggage or don't want to walk to the border, simply hop on one of the motorbike taxis or on a tuk-tuk for the 5 minute trip to the actual border, costing between 20 to 50 baht (depending on your bargaining skills).
It is inevitable that most of these "taxis" will drop you off at a big white building called "Visa Center" to get a visa into Cambodia. This is one of the many scams to get money out of you. Just alight from the motorbike or tuk-tuk and gently tell them you already have a visa. (information about scams in Poipet , Cambodia visa information )
Walk about 50 meters forward to the Thai passport control to cross the border. Foreigners (i.e. Non Thai/Cambodian) follow the right pointing arrow and go up the flight of stairs. Make sure you have your departure card ready, otherwise, pick one up from the table on the right of the room.
At the Border
Once you clear Thai passport control, if you have not already got your Cambodian visa you will cross the road and about 50 metres along on the right hand side is the visa office where you will be greeted by a man giving you a visa application form. Complete the form and you will see it also asks you for a passport photo. If you do not have a passport photo it is simply an additional charge of 100 Thai Baht. The visa will cost you $20 American dollars however it is also possible to pay in Thai Baht.
Once you are out of the visa office (or if you already have a visa, or an e-visa) walk about 200m to the Cambodian passport control section which is also on the right hand side of the road. Along the way, you will be hassled by dozens of touts trying to sell you taxi transportation to various destinations in Cambodia. Its safer to just ignore them and pretend you don't speak English. Progress to the cambodian border control. Depending on the time of day, be prepared for long queues. Here you might be approached by Cambodian officials in uniform asking if you want "express" service". Once again, politely decline, ask for the embarkation form and join the queue.
If you have an e-visa, walk directly to Passport Control on the right hand side of the road, fill out the arrival/departure form and hand a copy of your e-visa, the form and your passport over. There are also finger scanning facilities.
On the Cambodian side
Once you come out of the passport control office, you will find yourself in a "Free bus to Bus station" hall. If you decide to get on board one of these buses, it will take you to the International bus station which is 7km away, where you will be forced to use one of the more expensive buses that will take u directly to a guesthouse in either Siem Reap or Phnom Penh.
An alternative is to just walk straight on the main road past the big roundabout, for about 500 meters, where you will find signboards advertising buses with guys sitting in front of tables. The buses are infrequent and seem to leave in the morning or early evening though so determine if your waiting time is more important than your wallet size. There are also taxi's waiting around on the main raod near this part. Here you can negioate better prices. The average price (cost shown here in American $) per seat on a bus or taxi to Siem Reap and Battambang is between $5 to $7. You can pay for your ticket in American Dollars, Thai Baht or Cambodian Riel. Bus seats cost between $8 to $10 to Phnom Penh and $6 to $8 to Battambang.Note: Please keep your bags with you all the time as Poipet is one of the unsafest towns in Cambodia.